In the reaction,the acid obtained will be
$CH_3CHO + HCN \to CH_3CH(OH)CN \xrightarrow{H_2O} CH_3CH(OH)COOH$

  • A
    $D$-isomer
  • B
    $L$-isomer
  • C
    $(80\% \,D + 20\% \,L)$ mixture
  • D
    $(50\% \,D + 50\% \,L)$ mixture

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Which of the following compounds gives only a primary alcohol on reaction with a Grignard reagent $(RMgX)$?

The aldehydes which will not form a single Grignard product with one equivalent of Grignard reagent are:
$(a)$ Benzaldehyde
$(b)$ $4$-Formylbenzoic acid
$(c)$ $4$-Methoxybenzaldehyde
$(d)$ $4$-(Hydroxymethyl)benzaldehyde

The reactant is $3$-methylpentanal. The reaction with $NaCN$ followed by $H_2SO_4$ (cyanohydrin formation) is shown below:
$CH_3CH_2CH(CH_3)CH_2CHO \xrightarrow{NaCN/H^+} CH_3CH_2CH(CH_3)CH_2CH(OH)CN$
Products of the reaction are:

Assertion : Benzaldehyde is more reactive than ethanol towards nucleophilic attack.
Reason : The overall effect of $-I$ and $+R$ effect of phenyl group decreases the electron density on the carbon atom of $>C=O$ group in benzaldehyde.

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